Mega Man XZ: The Maverick Hunters

Zero's Techniques

Each time X, Zero or Axl defeat a stage boss, Zero receives a new technique that can be used at any time during the game. Each technique will add to his skills and enable him to perform special moves as well as new attacks.

Zero's Z-Saber Z-Saber Gained from: N/A
Zero brings his classic Z-Saber into action. This weapon has a long range combo attack which allows Zero to swing it a few times. During the game, he is able to learn new moves and techniques with the blade. These can be useful in many situations. Z-Saber
D-Glaive D-Glaive Gained from: Splash Warfly
The D-Glaive is gained once Splash Warfly is defeated. This is a water blade which has a very powerful blade at its end. Zero can use it to do a triple slash attack. D-Glaive
V-Hanger V-Hanger Gained from: Wind Crowrang
The V-Hanger is gained once Wind Crowrang is defeated. With these daggers equipped, Zero can slash non-stop. This allows him to do a powerful slashing strike. V-Hanger
All of Zero's techniques will require special button combinations to be used, and will involve the use of the normal fire button for the Z-Saber and the Special Weapon button. Each technique can be used an unlimited amount of times except for the Bakuenjin.
Special techniques
Gokumonken Gokumonken (Jail Gate Sword)

While standing still, hold the Square button.

The Gokumonken is learned once Soldier Stonekong is defeated. This allows Zero to protect himself with his sword. If any enemy touches him, he will do a counter attack. But he cannot counter enemy shots.
Raijinshou Raijinshou (Thunder God Rise)

While dashing, press the Triangle button.

The Raijinshou is learned once Tornado Tonion is defeated. This allows Zero to release a powerful electric tornado. Using this, he will also be able to fly up a bit in the air once it is released.
Suiretsusen Suiretsusen (Furious Water Flash)

Equip D-Glaive, then press the Triangle button.

The Suiretsusen is learned once Splash Warfly is defeated. This allows Zero to grab his weapon and do a powerful thrust attack. This is very powerful and very useful on strong enemies.
Bakuenjin Bakuenjin (Bursting Flame Array)

While standing still, press the R2 button.

The Bakuenjin is learned once Flame Hyenard is defeated. This technique allows Zero to punch the ground and release a storm of burning energy. This is very powerful and uses Giga Attack energy.
Zankourin Zankourin (Slicing Light Wheel)

While walking, press the Triangle button.

The Zankourin is learned once Ride Boarski is defeated. This allows Zero to make a powerful slash and release a wheel of light. This will roll over the ground and hit any obstacle in its way.
Hieijin Hieijin (Flying Shadow Blade)

While jumping, press the Triangle button.

The Hieijin is learned once Snipe Anteator is defeated. This allows Zero to release a homing missile into the air. It will fly right into its target and destroy it.
Souenbu Souenbu (Twin Swallow Dance)

Equip V-Hanger, then press the Triangle button.

The Souenbu is learned once Wind Crowrang is defeated. This allows Zero to release a tiny boomerang-like blade. It will fly sharply trough the air and cut any enemy into pieces, though it's very weak.
Hadangeki Hadangeki (Severing Wave Attack)

While standing still, press the Triangle button.

The Hadangeki is learned once Vanishing Gungaroo is defeated. This allows Zero to release a very powerful blast from his Z-Saber. This is one of his most powerful attacks.